Prof. S. Kruglikov

About Prof. S. Kruglikov

Mendeleyev University of Chemical Technology Moscow, Russia

The Use of Immersed Electrochemical Modules in Plating Shops for the Regeneration of Process Solutions and Purification of Water in Reclaim Tanks

  • Tab. 1: Applications of electrochemical processes for the regeneration of chromate-based solutions
    Tab. 1: Applications of electrochemical processes for the regeneration of chromate-based solutions

Immersed electrochemical module (IEM) is an electrochemical half-cell with one or two ion-exchange membranes and an inner electrode. IEM is immersed directly into a tank with a process solution in order to produce certain changes in its composition, for example, to recover nickel ions from spent electroless nickel plating solutions. Another area of application is to maintain the stable composition of process solutions such as various etchants used in the manufacture of PCBs, stripping and passivating solutions based on chromic acid and its salts. Stabilizing is achieved by anodic regeneration of an oxidant (chromate, ferric, cupric or persulfate ions) which are consumed in the course of the operation of the solution, by removing accumulating reaction products (various metal ions) and maintaining desirable pH value in the process solution. Continuous operation of such modules allows to eliminate periodic dumping and to reduce considerably consumption of chemicals used for replenishments. IEMs are used in many plating shops for continuous regeneration of chromate-based zinc passivating solutions. Another area of application of IMF is a continuous purification of water in reclaim tanks which allows to reduce the consumption of fresh water for rinsing and the amount of waste water. Metals such as zinc, copper, cadmium and tin are recovered from reclaim tanks equipped with IEMs and are usually returned into plating tanks. Nickel metal is utilized in some other way. Chromic acid which is recovered from reclaim tanks with IEMs contains no cationic impurities. It is returned into chromium plating or passivating process solutions. The operation of IEMs in reclaim tanks after chromium plating, anodizing or passivating in chromate-containing solutions allows to reduce the consumption of chemicals and the amount of waste. Installation of IEM does not need any additional floor space, pipe lines, etc. They are especially effective in chromating tanks and small-scale cadmium plating lines, where their use can solve problems related with the environment protection. IEMs are used in Russia in many captive plating shops.


    

Vladimir N. Kudryavtsev passed away on Thursday, October 31, 2013

Vladimir Kudryavtsev

Doctor of Science, Professor, Head of the Department of Electrochemical Engineering of the Mendeleyev University of Chemical Technology

Vladimir Kudryavtsev was born in Moscow on May 24, 1935 in an academic family. His father , Nikolay T Kudryavtsev, Dr. Sci. Professor was a prominent scientist in the field of electrochemical engineering, especially in electroplating , and at that time he was a Head of the Department of Electrochemical Engineering at the Mendeleyev Institute of Chemical Technology (now – Mendeleyev University). His experience, close cooperation with soviet plating industries turned to be powerful attraction for his son and for his choice of his future. Continue reading…